Synthetic routes to [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) complexes.
نویسندگان
چکیده
New procedures for the synthesis of [Au(NHC)(OH)] are reported. Initially, a two-step reaction via the digold complex [{Au(NHC)}(2)(μ-OH)][BF(4)] was probed, enabling the preparation of the novel [Au(SIPr)(OH)] complex and of its previously reported congener [Au(IPr)(OH)]. After further optimization, a one-step procedure was developed.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 41 18 شماره
صفحات -
تاریخ انتشار 2012